资源类型

期刊论文 917

会议视频 16

年份

2023 76

2022 98

2021 76

2020 47

2019 46

2018 39

2017 36

2016 39

2015 46

2014 50

2013 44

2012 55

2011 36

2010 49

2009 39

2008 34

2007 33

2006 15

2005 8

2004 9

展开 ︾

关键词

水资源 16

细水雾 14

可持续发展 6

泥水盾构 6

反渗透 5

水环境 4

环境 4

砂卵石地层 4

超滤 4

三峡工程 3

优化 3

农业节水 3

半旱地农业 3

绿色化工 3

Preissmann格式 2

中国西北地区 2

京津冀 2

光催化 2

养殖模式 2

展开 ︾

检索范围：

排序： 展示方式：

Single and joint effects of HHCB and cadmium on zebrafish (

Lei ZHANG, Jing AN, Qixing ZHOU

《环境科学与工程前沿（英文）》 2012年 第6卷 第3期   页码 360-372 doi: 10.1007/s11783-011-0353-z

摘要： As an important type of emerging pollutants, ecological toxicity and risk of artificial musks are increasingly concerned. Thus, single and joint toxic effects of 1,3,4,6,7,8-hexahydro-4,6,6,7,8,8- hexamethylcyclopenta-gamma-2-benzopyran (HHCB) as one of the most widely applied artificial musks and cadmium (Cd) as an toxic metal on zebrafish ( ) were investigated by the exposure of zebrafish to various concentrations of HHCB or/and Cd in feculent water containing bedloads. The results indicated that the joint effect of HHCB and Cd changed during different exposure times within 120 h. The index of the antioxidant enzyme system including superoxide dismutase (SOD) and peroxidase (POD), and malondialdehyde (MDA) were sensitive and induced in the zebrafish stressed by Cd, and content of soluble protein (SP) was sensitive to HHCB and could be used as a biomarker for HHCB. Joint effects on antioxidant enzymes depended more on the effect of single Cd in the first one or two days. However, in the rest exposure days, the effect of HHCB began to dominate in the joint effect during the exposure process.

关键词： 1     3     4     6     7     8-hexahydro-4     6     6     7     8     8-hexamethylcyclopenta-gamma-2-benzopyran (HHCB)     cadmium (Cd)     antioxidant biomarker     feculent water containing bedloads    

HTML PDF 收藏

Continuous flow removal of acid fuchsine by dielectric barrier discharge plasma water bed enhanced by

Rusen Zhou, Renwu Zhou, Xianhui Zhang, Kateryna Bazaka, Kostya (Ken) Ostrikov

《化学科学与工程前沿（英文）》 2019年 第13卷 第2期   页码 340-349 doi: 10.1007/s11705-019-1798-z

摘要： Continuous processes which allow for large amount of wastewater to be treated to meet drainage standards while reducing treatment time and energy consumption are urgently needed. In this study, a dielectric barrier discharge plasma water bed system was designed and then coupled with granular activated carbon (GAC) adsorption to rapidly remove acid fuchsine (AF) with high efficiency. Effects of feeding gases, treatment time and initial concentration of AF on removal efficiency were investigated. Results showed that compared to the N and air plasmas treatments, O plasma processing was most effective for AF degradation due to the strong oxidation ability of generated activated species, especially the OH radicals. The addition of GAC significantly enhanced the removal efficiency of AF in aqueous solution and shorten the required time by 50%. The effect was attributed to the ability of porous carbon to trap and concentrate the dye, increasing the time dye molecules were exposed to the plasma treated solution, and to enhance the production of OH radicals on/in GAC to boost the degradation of dyes by plasma as well as in situ regenerate the exhausted GAC. The study offers a new opportunity for continuous effective remediation of wastewater contaminated with organic dyes using plasma technologies.

关键词： continuous removal     dye-containing wastewater     dielectric barrier discharge     plasma water bed     activated carbon adsorption    

HTML PDF 收藏

Extractive desulfurization of model fuels with a nitrogen-containing heterocyclic ionic liquid

《化学科学与工程前沿（英文）》 2022年 第16卷 第12期   页码 1735-1742 doi: 10.1007/s11705-022-2167-x

摘要： A nitrogen-containing ionic liquid was synthesized using an aromatic nitrogen-containing heterocyclic and an amino acid, and applied to the extractive desulfurization process to remove benzothiophene, dibenzothiophene, and 4,6-dimethyldibenzothiphene from a model fuel oil. Chemical characterizations and simulation using Gaussian 09 software confirmed the rationality of an ionic liquid structure. Classification of non-covalent interactions between the ionic liquid and the three sulfur-containing contaminants was studied by reduced density gradient analysis. The viscosity of the ionic liquid was adjusted by addition of polyethylene glycol. Under extraction conditions of the volume of ionic liquid to oil as 1:1 and temperature as room temperature, the desulfurization selectivity of ionic liquid followed the order of 4,6-dimethyldibenzothiphene (15 min) < benzothiophene (15 min) ≈ dibenzothiophene (10 min). Addition of p-xylene and cyclohexene to the fuel oil had little effect. The extractant remained stable and effective after multiple regeneration cycles.

关键词： extractive desulfurization     nitrogen-containing heterocyclic ionic liquid     reduced density gradient analysis     desulfurization selectivity    

HTML PDF 收藏

Lithium-based draw solute for forward osmosis to treat wastewater discharged from lithium-ion battery manufacturing

《化学科学与工程前沿（英文）》 2022年 第16卷 第5期   页码 755-763 doi: 10.1007/s11705-022-2137-3

摘要： As draw solute is the core element of forward osmosis (FO) technology, here Li-Bet-Tf2N synthesized from a customized ionic liquid betainium bis(trifluoromethylsulfonyl)imide ([Hbet][Tf2N]) and Li2CO3 recovered from lithium-ion battery (LIB) wastes is proposed as a novel draw solute to treat Li+-containing wastewater from LIB manufacturing through FO filtration. Having high dissociation ability and an extended structure, Li-Bet-Tf2N generates a sufficiently high osmotic pressure to drive the FO filtration efficiently along with insignificant reverse solute diffusion. Li-Bet-Tf2N produces a water flux of 21.3 L·(m2·h)−1 at 1.0 mol∙L–1 against deionized water, surpassing conventional NaCl and MgCl2 draw solutes with a higher water recovery efficiency and a smaller solute loss. Li-Bet-Tf2N induces a more stable and higher water permeation flux with a 10.0% water flux decline than NaCl and MgCl2 for which the water fluxes decline 16.7% and 16.4%, respectively, during the treatment of 2000 mg∙L–1 Li+-containing wastewater for 12 h. More remarkably, unlike other draw solutes which require intensive energy input and complicated processes in recycling, Li-Bet-Tf2N is easily separated from water via solvent extraction. Reproducible results are achieved with the recycled Li-Bet-Tf2N. Li-Bet-Tf2N thus demonstrates a novel class of draw solute with great potentials to treat wastewater economically.

关键词： forward osmosis     lithium-ion battery     draw solution     lithium-containing wastewater     water treatment    

HTML PDF 收藏

Flux-free brazing of Mg-containing aluminium alloys by means of cold spraying

BOBZIN Kirsten, ZHAO Lidong, ERNST Felix, RICHARDT Katharina

《机械工程前沿（英文）》 2008年 第3卷 第4期   页码 355-359 doi: 10.1007/s11465-008-0055-9

摘要： In the present study, AlSi12 and AlSi10Cu4 were deposited onto Mg-containing aluminium alloys 6063 and 5754 by cold spraying. The influences of the two brazing alloys and spray parameters on coating formation were investigated. The microstructure of the coatings was characterized. Some coated samples were heat-treated at 590°C and 560°C in air to investigate the effect of the rupture of oxide scales on the diffusion of elements during heat-treatment. Some coated samples were brazed under argon atmosphere without any fluxes. The results show that AlSi12 had much better deposition behaviour than AlSi10Cu4. Due to the rupture of oxide scales, Cu and Si diffused into the substrate and a metallurgical bond formed between the brazing alloys and the substrates during heat-treatment. The coated samples could be brazed without any fluxes. Because the oxide scales prevented the formation of a metallurgical bond locally, the brazed samples had relatively low shear strengths of up to 43 MPa.

关键词： diffusion     metallurgical     substrate     Mg-containing aluminium     spraying    

HTML PDF 收藏

Stability analysis of alkaline nitrobenzene-containing wastewater by a catalyzed Fe-Cu treatment process

FAN Jinhong, XU Wenying, GAO Tingyao, MA Luming

《环境科学与工程前沿（英文）》 2007年 第1卷 第4期   页码 504-508 doi: 10.1007/s11783-007-0081-6

摘要： Iron and copper bimetallic system (catalyzed Fe-Cu process) is a promising technology for alkaline nitrobenzene-containing wastewater treatment. However, little is currently known about the changes of treatment efficiency with time

关键词： technology     bimetallic     catalyzed     nitrobenzene-containing wastewater     efficiency    

HTML PDF 收藏

Construction of defect-containing UiO-66/MoSe heterojunctions with superior photocatalytic performance

《化学科学与工程前沿（英文）》 2023年 第17卷 第4期   页码 449-459 doi: 10.1007/s11705-022-2226-3

摘要： Metal–organic frameworks are recognized as promising multifunctional materials, especially metal–organic framework-based photocatalysts, which are considered to be ideal photocatalytic materials. Herein, a new type of UiO-66/MoSe2 composite was prepared using the solvothermal method. The optimum composite was selected by adjusting the mass ratio of UiO-66 and MoSe2. X-ray diffraction analysis showed that the mass ratio influenced the crystal plane exposure rate of the composite, which may have affected its photocatalytic performance. The composite is composed of ultra-thin flower-like MoSe2 that wrapped around cubic UiO-66, a structure that increases the abundance of active sites for reactions and is more conducive to the separation of carriers. The photocatalytic properties of the composite were evaluated by measuring the degradation rate of Rhodamine B and the catalyst’s ability to reduce Cr(VI)-containing wastewater under visible light irradiation. Rhodamine B was decolorized completely in 120 min, and most of the Cr(VI) was reduced within 150 min. The photochemical mechanism of the complex was studied in detail. The existence of Mo6+ and oxygen vacancies, in addition to the Z-type heterojunction promote the separation of electrons and holes, which enhances the photocatalytic effect.

关键词： UiO-66/MoSe2     photocatalysis     dye-containing wastewater     heavy metal wastewater     oxygen vacancies    

HTML PDF 收藏

Spray characteristics and controlling mechanism of fuel containing CO

Zhen HUANG, Jin XIAO, Xinqi QIAO, Gaozhi JIANG, Yiming SHAO, Seiichi SHIGA, Yasuhiro DAISHO

《能源前沿（英文）》 2012年 第6卷 第1期   页码 80-88 doi: 10.1007/s11708-012-0180-3

摘要： This paper presents studies of spray characteristics and controlling mechanism of fuel containing CO . Using diesel fuel containing CO gas, experiments were conducted on diesel hole-type nozzles and simple nozzles. The steady spray and transient spray characteristics were observed and measured by instantaneous shadowgraphy, high-speed photography, phase Doppler anemometry (PDA) and LDSA respectively. The effects of CO concentration in the fuel, the injection pressure, the nozzle ratio, surrounding gas pressure and temperature on the atomization behavior and spray pattern were evaluated. The results show that the injection of fuel containing CO can greatly improve the atomization and produce a parabolic-shaped spray; and the CO gas concentration, surrounding gas pressure, temperature and nozzle configuration have dominant influences on spray characteristics of the fuel containing CO . New insight into the controlling mechanism of atomization of the fuel containing CO was provided.

关键词： spray characteristics     fuel atomization     fuel containing CO2    

HTML PDF 收藏

Role of oxygen vacancy inducer for graphene in graphene-containing anodes

《化学科学与工程前沿（英文）》 2023年 第17卷 第3期   页码 326-333 doi: 10.1007/s11705-022-2213-8

摘要： Currently, graphene is only considered as a conductive additive and expansion inhibitor in oxides/graphene composite anodes. In this study, a new graphene role (oxygen vacancy inducer) in graphene/oxides composites anodes, which are treated at high-temperature, is proposed and verified using experiments and density functional theory calculations. During high-temperature processing, graphene forms carbon vacancies due to increased thermal vibration, and the carbon vacancies capture oxygen atoms, facilitating the formation of oxygen vacancies in oxides. Moreover, the induced oxygen vacancy concentrations can be regulated by sintering temperatures, and the behavior is unaffected by oxide crystal structures (crystalline and amorphous) and morphology (size and shape). According to density functional theory calculations and electrochemical measurements, the oxygen vacancies enhance the lithium-ion storage performance. The findings can result in a better understanding of graphene’s roles in graphene/oxide composite anodes, and provide a new method for designing high-performance oxide anodes.

关键词： oxide     oxygen vacancy     graphene     anode     density functional theory calculation    

HTML PDF 收藏

Solid-state NMR for metal-containing zeolites: From active sites to reaction mechanism

Xingling Zhao, Jun Xu, Feng Deng

《化学科学与工程前沿（英文）》 2020年 第14卷 第2期   页码 159-187 doi: 10.1007/s11705-019-1885-1

摘要： Metal-containing zeolite catalysts have found a wide range of applications in heterogeneous catalysis. To understand the nature of metal active sites and the reaction mechanism over such catalysts is of great importance for the establishment of structure-activity relationship. The advanced solid-state NMR (SSNMR) spectroscopy is robust in the study of zeolites and zeolite-catalyzed reactions. In this review, we summarize recent developments and applications of SSNMR for exploring the structure and property of active sites in metal-containing zeolites. Moreover, detailed information on host-guest interactions in the relevant zeolite catalysis obtained by SSNMR is also discussed. Finally, we highlight the mechanistic understanding of catalytic reactions on metal-containing zeolites based on the observation of key surface species and active intermediates.

关键词： metal-containing zeolites     solid-state NMR     active site     host-guest interaction     reaction mechanism    

HTML PDF 收藏

Diversity and distribution of proteorhodopsin-containing microorganisms in marine environments

Bo WEI

《环境科学与工程前沿（英文）》 2012年 第6卷 第1期   页码 98-106 doi: 10.1007/s11783-010-0278-y

摘要： Proteorhodopsin (PR) is a recently discovered protein involved in the utilization of light energy. Several studies have shown that PR-containing microorganisms are widespread and compose a large proportion of the biomass in marine ecosystems. A better understanding of the ecological role of PR will help clarify the effect of the global flow of energy and the carbon cycle on marine communities. In this study, a bioinformatical database of PR codon sequences, the Global Distribution Database of Proteorhodopsin (GDDP), as a tool for analyzing the diversity and distribution of PR-containing microorganisms in marine environments throughout the world was designed. The community structure of PR microorganisms were also compared using PCR assays and UniFrac analyses of 12 samples collected from three water layers (0, 75, and 200 m) at four representative sites in the Pacific, Atlantic, and Indian Oceans. The results indicate that PR-containing microorganisms can be grouped into two distribution types: widespread and location-specific. Representative cases of the former include SAR11-PR and HOT2C01-PR. Interestingly, PR communities cluster by geographic locale but not by water depth.

关键词： proteorhodopsin (PR)     microorganism community     diversity     marine environments    

HTML PDF 收藏

Optimizing iodine capture performance by metal–organic framework containing with bipyridine units

《化学科学与工程前沿（英文）》 2023年 第17卷 第4期   页码 395-403 doi: 10.1007/s11705-022-2218-3

摘要： Radioactive iodine exhibits medical values in radiology, but its excessive emissions can cause environmental pollution. Thus, the capture of radioiodine poses significant engineering for the environment and medical radiology. The adsorptive capture of radioactive iodine by metal–organic frameworks (MOFs) has risen to prominence. In this work, a Th-based MOF (denoted as Th-BPYDC) was structurally designed and synthesized, consisting of [Th6(μ3-O)4(μ3-OH)4(H2O)6]12+ clusters, abundant bipyridine units, and large cavities that allowed guest molecules diffusion and transmission. Th-BPYDC exhibited the uptake capacities of 2.23 g·g−1 and 312.18 mg·g−1 towards I2 vapor and I2 dissolved in cyclohexane, respectively, surpassing its corresponding analogue Th-UiO-67. The bipyridine units boosted the adsorption performance, and Th-BPYDC showed good reusability with high stability. Our work thus opened a new way for the synthesis of MOFs to capture radioactive iodine.

关键词： metal–organic framework     iodine     adsorption     nuclear waste     environmental remediation    

HTML PDF 收藏

Coextraction of vanadium and manganese from high-manganese containing vanadium wastewater by a solvent

Zishuai Liu, Yimin Zhang, Zilin Dai, Jing Huang, Cong Liu

《化学科学与工程前沿（英文）》 2020年 第14卷 第5期   页码 902-912 doi: 10.1007/s11705-019-1887-z

摘要： High-manganese containing vanadium wastewater (HMVW) is commonly produced during the vanadium extraction process from vanadium titano-magnetite. HMVW cannot be reused and discharged directly, and is harmful to the environment and affect product quality due to heavy metals in the wastewater. The wastewater is usually treated by lime neutralization, but valuable metals (especially V and Mn) cannot be recovered. In this study, an efficient and environmentally friendly method was developed to recover valuable metals by using a solvent extraction-precipitation process. In the solvent extraction process, 98.15% of vanadium was recovered, and the V O product, with a purity of 98.60%, was obtained under optimal conditions. For the precipitation process, 91.05% of manganese was recovered as MnCO which meets the III grade standard of HG/T 2836-2011. Thermodynamic simulation analysis indicated that MnCO was selectively precipitated at pH 6.5 while Mg and Ca could hardly be precipitated. The results of X-ray diffraction and scanning electron microscopy demonstrated that the obtained V O and MnCO displayed a good degree of crystallinity. The treated wastewater can be returned for leaching, and resources (V and Mn) in the wastewater were utilized efficiently in an environmentally friendly way. Therefore, this study provides a novel method for the coextraction of V and Mn from HMVW.

关键词： high-manganese containing vanadium wastewater     solvent extraction     carbonate precipitation     vanadium titano-magnetite     valuable metal recovery    

HTML PDF 收藏

化学强化反冲洗缓解超滤处理含藻地表水的膜污染机制及调控——从小试到生产示范研究 Article

唐小斌, 郭铁城, 常海庆, 岳霄, 王金龙, 于海宽, 谢冰涵, 朱学武, 李圭白, 梁恒

《工程（英文）》 2022年 第19卷 第12期   页码 40-49 doi: 10.1016/j.eng.2021.01.013

摘要：

超滤（UF）工艺已广泛应用于饮用水处理中。然而，藻类及其分泌物会导致严重的膜污染，在实际生产过程中对超滤工艺构成巨大挑战。本文开发了一种简单实用的化学强化反冲洗（CEB）技术，考察了次氯酸钠（NaClO）、氯化钠（NaCl）、氢氧化钠（NaOH）、柠檬酸钠及其组合对藻源膜污染的控制效能。结果表明，化学清洗剂的类型是影响超滤膜水力不可逆膜污染（HIMF）的关键因素。其中，NaClO 对HIMF的控制效果最佳，其次是NaCl。此外，与单独使用NaClO相比，将NaClO与NaCl、NaOH或柠檬酸钠等组合使用对HIMF的控制效果并没有明显提升。NaClO 的最优投加量和投加方案为10 mg∙L−1，且最佳投加频次为每天两次。通过开展长周期的中试和生产实验进一步表明CEB技术可有效缓解藻源膜污染，尤其是HIMF。此外，与不添加化学药剂的常规水力反冲洗相比，CEB技术主要是通过氧化作用有效地去除包括生物聚合物、腐殖质和蛋白质类物质等在内的有机污染物，削弱有机污染物与膜表面之间的黏附力，从而显著降低HIMF。因此，CEB技术可在低药剂条件下有效地缓解藻源膜污染，是一种有效阻控超滤处理含藻地表水过程膜污染的方法。

关键词： 超滤     膜污染     水力不可逆的膜污染     化学强化反冲洗（CEB）     含有藻类的地表水    

HTML PDF 收藏

Linear viscoelastic behavior of asphalt binders and mixtures containing very high percentages of reclaimed

《结构与土木工程前沿（英文）》   页码 1211-1227 doi: 10.1007/s11709-023-0983-9

摘要： The primary aim of this study is to correlate the impact of aggregates, if any, on the viscoelastic behavior of rejuvenated asphalt mixtures containing very high amounts of reclaimed asphalt pavement (RAP) (> 50%). First, gradation of 100% RAP was rectified, using a modified Bailey method by adding virgin aggregates to achieve two coarse dense-graded and one fine dense-graded blends. Complex modulus test was then performed from −35 to +35 °C and 0.01–10 Hz. In addition to performance grade (PG) testing, extracted and recovered binders from different asphalt mixtures underwent shear complex modulus test within −8 °C to high temperature PG and frequencies from 0.001 to 30 Hz. Cole−Cole, Black space, complex modulus and phase angle master curves were constructed and Shift-Homothety-Shift in time-Shift (SHStS) transformation was used to compare the linear viscoelastic behavior of asphalt binders and mixtures. The influence of aggregates on the viscoelastic behavior of asphalt mixtures depends on temperature and/or frequency. The role of asphalt binders in the behavior of asphalt mixtures is more pronounced at high temperatures and the effect of the aggregate structure increases as the temperature falls. The maximum difference (60% to 70%) in the viscoelastic behavior of the binder and mixture based on SHStS transformed Cole−Cole curves is within the phase angle of 15°–20°.

关键词： RAP     complex modulus     SHStS transformation     rejuvenation     behavior of asphalt binder and mixture    

HTML PDF 收藏

标题 作者 时间 类型 操作

Single and joint effects of HHCB and cadmium on zebrafish (

Lei ZHANG, Jing AN, Qixing ZHOU

期刊论文

Continuous flow removal of acid fuchsine by dielectric barrier discharge plasma water bed enhanced by

Rusen Zhou, Renwu Zhou, Xianhui Zhang, Kateryna Bazaka, Kostya (Ken) Ostrikov

期刊论文

Extractive desulfurization of model fuels with a nitrogen-containing heterocyclic ionic liquid

期刊论文

Lithium-based draw solute for forward osmosis to treat wastewater discharged from lithium-ion battery manufacturing

期刊论文

Flux-free brazing of Mg-containing aluminium alloys by means of cold spraying

BOBZIN Kirsten, ZHAO Lidong, ERNST Felix, RICHARDT Katharina

期刊论文

Stability analysis of alkaline nitrobenzene-containing wastewater by a catalyzed Fe-Cu treatment process

FAN Jinhong, XU Wenying, GAO Tingyao, MA Luming

期刊论文

Construction of defect-containing UiO-66/MoSe heterojunctions with superior photocatalytic performance

期刊论文

Spray characteristics and controlling mechanism of fuel containing CO

Zhen HUANG, Jin XIAO, Xinqi QIAO, Gaozhi JIANG, Yiming SHAO, Seiichi SHIGA, Yasuhiro DAISHO

期刊论文

Role of oxygen vacancy inducer for graphene in graphene-containing anodes

期刊论文

Solid-state NMR for metal-containing zeolites: From active sites to reaction mechanism

Xingling Zhao, Jun Xu, Feng Deng

期刊论文

Diversity and distribution of proteorhodopsin-containing microorganisms in marine environments

Bo WEI

期刊论文

Optimizing iodine capture performance by metal–organic framework containing with bipyridine units

期刊论文

Coextraction of vanadium and manganese from high-manganese containing vanadium wastewater by a solvent

Zishuai Liu, Yimin Zhang, Zilin Dai, Jing Huang, Cong Liu

期刊论文

化学强化反冲洗缓解超滤处理含藻地表水的膜污染机制及调控——从小试到生产示范研究

唐小斌, 郭铁城, 常海庆, 岳霄, 王金龙, 于海宽, 谢冰涵, 朱学武, 李圭白, 梁恒

期刊论文

Linear viscoelastic behavior of asphalt binders and mixtures containing very high percentages of reclaimed

期刊论文